You could use the CURL command to trigger the caching of a particular VOD asset, but you will need to send a CURL command to get the initial playlist.m3u8 and the chunklist.m3u8 playlists, and then send additional CURL requests for each of the .ts data chunks found in the chunklist. This way you can make sure that the entire VOD asset is cached locally on your Wowza server.
I will also send this workflow to our product management team to take it into consideration as a future Wowza feature.